To make the solution more purple, you would want to increase the concentration of MnO4– ions. According to the given equilibrium reaction:
\[ 3 \text{MnO}_4^{2-} (aq) + 4 \text{H}^+ (aq) \rightleftharpoons 2 \text{MnO}_4^{-} (aq) + 2 \text{H}_2\text{O} (l) + \text{MnO}_2 (s) \]
Adding MnO4– ions directly to the solution would increase their concentration and thus make the solution more purple.
So the correct response is: MnO4– ions.