From the information given, the most accurate deduction is that "The volcano released a lot of sulfur dioxide and ash."
The eruption of Mt. Pinatubo in 1991 released significant amounts of sulfur dioxide and ash particles into the atmosphere. These particles reflect sunlight away from the Earth, leading to a cooling effect on the Earth's surface for a period of time, which aligns with the cooling described in the information provided. The other statements do not directly relate to the context of the volcano's eruption and its effects on the Earth's climate.