Question

Solid carbon dioxide is commonly known as dry ice. Carbon dioxide freezes at a temperature of -78.5°C, which makes dry ice very good at keeping things cold. Liquid carbon dioxide does not exist at atmospheric pressure. Because of this, dry ice immediately changes to a gaseous state when it is warmed. This can be seen as a benefit of using dry ice, since no liquid is left in the container that is being used to keep things cold. A shipping company wants to determine how effectively dry ice can keep food frozen in a cooler system over time. A scientist at the company places a block of dry ice in a cooler and closes the lid. The picture shows the dry ice being put into the cooler.



The scientist uses an infrared thermometer to measure the temperature of the air inside the cooler over a period of 48 hours. The data collected is shown in the graph.

The graph shows 'Temperature in degrees Celsius' along the vertical axis in increments of 20 degrees, from minus 100 to 20 degrees. Along the horizontal axis is 'Time in hours,' in increments of 6 hours, from 0 to 48 hours. A line indicating 'temperature inside the cooler' starts at 20 degrees and drops rapidly to a point between minus 60 degrees and minus 80 degrees, before 6 hours. The line then drops slowly to nearly minus 80 degrees by 12 hours. After that, the line shows a slow and steady increase in temperature— it crosses minus 60 degrees by 36 hours and reaches a point between minus 20 and minus 40 degrees, by 48 hours.

Multiple Select Question
Which statements correctly describe how the energy of the carbon dioxide molecules in the dry ice changes during the first 12 hours of the experiment? Choose the two correct answers.

A.
As the average number of molecules in the cooler decreased, the thermal energy also decreased.

B.
The average kinetic energy of the carbon dioxide molecules increases as it becomes a gas.

C.
The average thermal energy of the air in the cooler increases throughout the experiment.

D.
The average thermal energy of carbon dioxide decreases throughout the experiment.

E.
As dry ice changes from a solid to a gas, it absorbs thermal energy from the surrounding air.

Answers

GPT-4o mini
To analyze how the energy of the carbon dioxide molecules in the dry ice changes during the first 12 hours of the experiment, we can consider the physical processes occurring as the dry ice sublimates and the temperature inside the cooler changes.

The correct answers from the choices provided are:

**B.** The average kinetic energy of the carbon dioxide molecules increases as it becomes a gas.
**E.** As dry ice changes from a solid to a gas, it absorbs thermal energy from the surrounding air.

### Explanation:
- **B** is correct because as the dry ice (solid carbon dioxide) sublimates into gas, the molecules gain kinetic energy, which translates to an increase in temperature of the gas formed.
- **E** is correct since sublimation is an endothermic process; dry ice absorbs heat from its surroundings (the air in the cooler) in order to change from solid to gas, which leads to a decrease in the temperature of that surrounding air.

The other options are incorrect for the following reasons:
- **A** is incorrect because there isn't a decrease in the average number of molecules; the number will change in terms of phase, but not decrease in that context.
- **C** is incorrect because the average thermal energy of the air in the cooler actually decreases as the dry ice sublimates, causing the air temperature to drop.
- **D** is partially misleading; while it is true that the thermal energy of the carbon dioxide (solid) decreases as it transitions to a gas, the phrasing creates ambiguity in understanding the entire process, especially considering the overall energy dynamics in the cooler.