Yes, rhyme often involves a relationship between stressed and unstressed syllables. In poetry, rhyme typically occurs at the end of lines and can involve a variety of metrical patterns. The arrangement of stressed (accented) and unstressed (unaccented) syllables contributes to the rhythm and flow of the poem.
In many types of traditional verse, like iambic pentameter, a specific pattern of stressed and unstressed syllables is established, which can enhance the effect of the rhyme. For example, in iambic pentameter, each line consists of five iambs, which are metrical feet made up of one unstressed syllable followed by one stressed syllable (da-DUM).
Overall, the interplay between stressed and unstressed syllables is a crucial aspect of both the rhythm and rhyme in poetry.