Based on the information provided about the food web, the animal that is most likely to be a keystone species would be the frog.
Keystone species play a crucial role in maintaining the structure of a community. Frogs, as consumers at the first level, likely serve as both prey and predators in their ecological niche, helping to regulate both plant populations and the populations of insects and smaller vertebrates. The other options (grasshopper, mouse, and deer) do not play as significant a role in the ecological balance compared to frogs, which contribute to both predator and prey dynamics.