Since ∠A and ∠B are vertical angles, they are equal, which means m∠B = m∠A. Given that m∠A = 22°, we have m∠B = 22° as well. Since ∠B is complementary to ∠C, the sum of their measures is 90°. Therefore, we can express this relationship with the equation m∠B + m∠C = 90°. Substituting the value of m∠B, the equation becomes 22° + m∠C = 90°.
Thus, the equation to solve for m∠C is 22° + m∠C = 90°.