To subtract the numbers \(4.66 \times 10^{-5}\) and \(7.34 \times 10^{-7}\), we first need to express them with the same exponent.
Convert \(4.66 \times 10^{-5}\) to have the same exponent as \(7.34 \times 10^{-7}\):
\[ 4.66 \times 10^{-5} = 4.66 \times 10^{-5} \times \frac{100}{100} = 4.66 \times 10^{-5} \times 10^{2} = 4.66 \times 10^{-7} \times 100 \]
So we can write: \[ 4.66 \times 10^{-5} = 466 \times 10^{-7} \]
Now we perform the subtraction:
\[ 466 \times 10^{-7} - 7.34 \times 10^{-7} \]
Subtracting the numbers:
\[ (466 - 7.34) \times 10^{-7} = 458.66 \times 10^{-7} \]
Next, we can express that in scientific notation:
\[ 458.66 \times 10^{-7} = 4.5866 \times 10^{-5} \]
So the final answer is:
\[ \boxed{4.5866 \times 10^{-5}} \]