To complete the square for the quadratic expression \( z^2 + 20z + __ \), we need to find the number that makes it a perfect square.
- Take the coefficient of \( z \), which is 20.
- Divide it by 2: \( \frac{20}{2} = 10 \).
- Square that result: \( 10^2 = 100 \).
So, we need to add \( 100 \) to the expression.
Thus, the completed expression is:
\[ z^2 + 20z + 100 = (z + 10)^2 \]
The number that makes the polynomial a perfect-square quadratic is \(\boxed{100}\).