To express the numbers in scientific notation, we convert each number into the form \( a \times 10^n \), where \( 1 \leq a < 10 \) and \( n \) is an integer.
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For \( 654,987,034 \): \[ 654,987,034 = 6.54987034 \times 10^8 \]
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For \( 645,897,430 \): \[ 645,897,430 = 6.45897430 \times 10^8 \]
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For \( 546,789,340 \): \[ 546,789,340 = 5.46789340 \times 10^8 \]
Now let's compare the values of \( a \):
- \( 6.54987034 \)
- \( 6.45897430 \)
- \( 5.46789340 \)
The greatest value among these is \( 6.54987034 \), which corresponds to the number \( 654,987,034 \).
Thus, the number with the greatest value in scientific notation is: \[ \boxed{6.54987034 \times 10^8} \]