Since angles A and B are complementary, we know that:
\[ m∠A + m∠B = 90° \]
Given that \( m∠A = x° \) and \( m∠B = 2x° \), we can substitute these into the equation:
\[ x + 2x = 90° \]
This simplifies to:
\[ 3x = 90° \]
Now, divide both sides by 3:
\[ x = 30° \]
Now that we have the measure of angle A:
\[ m∠A = x = 30° \]
Next, we find the measure of angle B:
\[ m∠B = 2x = 2(30°) = 60° \]
Therefore, the measure of angle B is:
\[ \boxed{60°} \]