Under certain conditions, water can be separated into oxygen and hydrogen gases according to the equation 2H2O → 2H2 + O2.

In a lab, 112g of hydrogen gas and 888g of oxygen gas were collected. Student A says that the amount of water to start cannot be determined, but Student B says that the water must have been 1000g. Who is correct?

(1 point)
Responses

Student B, because of the law of conservation of matter.
Student B, because of the law of conservation of matter.

Neither are correct. It was 2000g because the equation shows 2H2O.
Neither are correct. It was 2000g because the equation shows 2H 2 O.

Neither are correct. It would have been 1112g, because there are 2 H2 to 1 O2.
Neither are correct. It would have been 1112g, because there are 2 H 2 to 1 O 2 .

Student A, because the water was not measured to start with.

1 answer

To determine the initial amount of water, we can use the law of conservation of mass, which states that matter cannot be created or destroyed in a chemical reaction. The reaction is:

\[ 2H_2O \rightarrow 2H_2 + O_2 \]

From the equation, we can see that 2 moles of water yield 2 moles of hydrogen gas and 1 mole of oxygen gas.

  1. Calculate the moles of H2 and O2 produced:

    • Molar mass of H2 = 2 g/mol \( \Rightarrow \) Moles of H2 from 112g = \( \frac{112g}{2g/mol} = 56 \) moles
    • Molar mass of O2 = 32 g/mol \( \Rightarrow \) Moles of O2 from 888g = \( \frac{888g}{32g/mol} = 27.75 \) moles
  2. From the balanced equation, 2 moles of H2O produce 2 moles of H2 and 1 mole of O2. This means:

    • The ratio of H2 to O2 in the reaction is 2:1.
    • Therefore, for every 2 moles of H2 produced, 1 mole of O2 is produced.
  3. The number of moles of H2 suggests twice the number of moles of O2 should be produced. Hence, for 56 moles of H2, we should have:

    • \( \text{Expected moles of O2} = \frac{56}{2} = 28 \)
  4. We have calculated through the mass of oxygen that we obtained \( 27.75 \) moles, which is very close to what we would expect if we started with water.

  5. Using the overall stoichiometry:

    • From 2 moles of H2O, we produce \( 2 \times 2 = 112 \) grams of H2 (which is correct)
    • From the same 2 moles of H2O, we produce \( 32 \) grams of O2

To find the total mass of the water, we add:

  • \( 112g \) of H2 + \( 888g \) of O2 = \( 1000g \)

Thus, the initial amount of water must have been \( 1000g \).

Therefore, the correct answer is:

Student B, because of the law of conservation of matter.