To find the probability of picking either number 2 or number 3 from the sample space \( S = {1, 2, 3} \), we first identify the favorable outcomes. The favorable outcomes are:
- Picking 2
- Picking 3
There are 2 favorable outcomes (2 and 3) out of a total of 3 possible outcomes in the sample space.
Thus, the probability \( P \) of picking either number 2 or number 3 can be calculated as follows:
\[ P(\text{picking 2 or 3}) = \frac{\text{Number of favorable outcomes}}{\text{Total number of outcomes}} = \frac{2}{3} \]
Therefore, the probability of picking number 2 or 3 is
\[ \frac{2}{3} \]
This is already in its simplest form.