In the given sample space \( S = {a, b, c, d, e, f} \), we identify the consonants. The letters are:
- Vowels: \( a, e \)
- Consonants: \( b, c, d, f \)
There are a total of 6 letters in the sample space. Among them, 4 are consonants: \( b, c, d, f \).
To calculate the probability of picking a consonant, we use the formula:
\[ \text{Probability of picking a consonant} = \frac{\text{Number of consonants}}{\text{Total number of outcomes}} = \frac{4}{6} \]
We can simplify \( \frac{4}{6} \):
\[ \frac{4}{6} = \frac{2}{3} \]
Therefore, the probability of picking a consonant is \( \frac{2}{3} \).
So the correct answer is \( \frac{2}{3} \).