The word you might be thinking of is "naive." It conveys a sense of innocence or a lack of sophistication, similar to being airheaded or pure, without the aloofness that you find in other terms. Another possibility could be "lighthearted," which implies a carefree and cheerful attitude while not being distant or detached. Would either of these suggestions work for you?
What word means like airheaded and pure, and not aloof even though aloof is a really cute word and should mean something like that
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