The measurement that will require the use of irrational numbers is the diagonal of one of the cube’s faces.
This is because the diagonal \(d\) of a square face of the cube can be calculated using the Pythagorean theorem:
\[ d = \sqrt{a^2 + a^2} = \sqrt{2a^2} = a\sqrt{2} \]
Since \(a\) is a rational number, \(a\sqrt{2}\) will be irrational because \(\sqrt{2}\) is an irrational number. Therefore, the correct response is the diagonal of one of the cube’s faces.