To calculate the perimeters of the squares, we use the formula for the perimeter of a square, which is given by:
\[ \text{Perimeter} = 4 \times \text{side length} \]
For the smaller square with a side length of 13 cm:
\[ \text{Perimeter of smaller square} = 4 \times 13 = 52 \text{ cm} \]
For the larger square with a side length of 39 cm:
\[ \text{Perimeter of larger square} = 4 \times 39 = 156 \text{ cm} \]
Now, to find the ratio of the perimeter of the larger square to the perimeter of the smaller square, we set up the ratio:
\[ \text{Ratio} = \frac{\text{Perimeter of larger square}}{\text{Perimeter of smaller square}} = \frac{156}{52} \]
To simplify this fraction, we divide both the numerator and the denominator by 52:
\[ \frac{156 \div 52}{52 \div 52} = \frac{3}{1} = 3 \]
Thus, the ratio of the perimeter of the larger square to that of the smaller square is:
\[ \frac{3}{1} \]
So, the final answer is \(\frac{3}{1}\).