The scenario that best demonstrates Newton's first law of motion is:
b A car passenger moves forward when a car suddenly stops.
Newton's first law states that an object at rest will remain at rest, and an object in motion will remain in motion with the same speed and in the same direction unless acted upon by an unbalanced force. In this scenario, the car is the object that is suddenly stopped (an external force is applied), but the passenger continues moving forward due to inertia.