Why do group 5A elements gain 3 electrons

They can actually gain or lose as many electrons as they want to become stable
The outer shell can hold 8 electrons. They have 5 outer (valence) electrons, so if they gain 3 more they will be stable
3 is the ideal number of electrons for every atom to gain
The outer shell can hold 3 electrons. If they gain 3 electrons they will have a full outer shell with a total of 3 valence electrons

1 answer

Group 5A elements (also known as Group 15 in the modern periodic table) typically have five valence electrons. The most stable electron configuration for any atom is achieved when its outer shell is filled with eight electrons, a condition known as the octet rule.

Why do Group 5A elements commonly gain three electrons?

  1. Existing Electron Count: Group 5A elements have five valence electrons. In order to achieve a full octet (eight electrons in their outer shell), they need to gain three additional electrons. Therefore, gaining three electrons allows them to reach this stable configuration.

  2. Energy Considerations: While it is theoretically possible for atoms to lose electrons, doing so tends to increase their energy when they transition from a native state (where they have five electrons) to a more ionic state (where they would lose electrons). Gaining electrons to reach a stable octet typically requires less energy compared to losing five electrons to achieve a positive charge.

  3. Ionic and Covalent Bonding: Many Group 5A elements, like nitrogen and phosphorus, tend to form anions (negatively charged ions) when they gain three electrons (e.g., the nitride ion \(N^{3-}\) and phosphide ion \(P^{3-}\)). This behavior leads to the formation of stable compounds.

  4. Chemical Stability: Gaining three electrons and forming bonds with other elements (through ionic or covalent bonding) allows these elements to achieve greater stability in their compounds.

In summary, Group 5A elements gain three electrons to satisfy the octet rule and achieve a more stable electronic configuration, which is energetically favorable. The misconception that "3 is the ideal number of electrons for every atom to gain" is not universally true; it specifically applies to Group 5A elements in the context of achieving stability through an octet. Each element has unique electron requirements based on its position in the periodic table.