Average kinetic energy of water molecules is directly related to the temperature of the water. The higher the temperature, the greater the average kinetic energy.
Given the temperatures:
- Sample L: 40 ºC
- Sample M: 88 ºC
- Sample N: 21 ºC
In order from greatest to least average kinetic energy, the samples should be arranged as follows:
- M (88 ºC)
- L (40 ºC)
- N (21 ºC)
Thus, the correct order is M, L, N.
So the answer is: M, L, N.