Let's analyze each scenario based on Le Chatelier's Principle, which states that if a system at equilibrium is disturbed, it will shift to counteract the disturbance.
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Experimenter ADDS heat to the closed system:
- The forward reaction produces heat (exothermic). Adding heat shifts the equilibrium to the left (toward reactants).
- Direction of shift: Reverse Reaction (shift left)
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Experimenter counts 2 moles of nitrogen and 6 moles of hydrogen gas, and 8 moles of ammonia:
- Moles: 2 (N2) + 6 (H2) ⇌ 8 (NH3)
- There are more product moles (8) than reactant moles (8 total, which is 2 + 6).
- This suggests the reaction favors products at this moment, but does not indicate a shift due to changes.
- No shift indicated for this scenario.
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Experimenter counts 1 mole of ammonia in the closed system:
- Moles: 2 (N2) + 6 (H2) ⇌ 1 (NH3)
- This indicates a higher concentration of reactants compared to products, implying a shift toward products.
- Direction of shift: Forward Reaction (shift right)
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Experimenter ADDS the catalyst of iron:
- A catalyst speeds up the rate of both the forward and reverse reactions equally but does not affect the position of equilibrium.
- No shift indicated (no change in direction).
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Experimenter REMOVES heat from the closed system:
- Removing heat shifts the equilibrium to the right (toward products, which release heat).
- Direction of shift: Forward Reaction (shift right)
In summary:
- ADDS heat: Shift left
- Counts 2 N2, 6 H2, 8 NH3: No shift
- Counts 1 NH3: Shift right
- ADDS catalyst: No shift
- REMOVES heat: Shift right