Kinetic energy of molecules is related to their temperature; higher temperatures generally indicate higher kinetic energy. In the provided data:
- Sample 1: 98.2 °C
- Sample 2: 46.0 °C
- Sample 3: 100.6 °C
- Sample 4: 31.4 °C
Sample 4 has the lowest temperature (31.4 °C), which means it also has the lowest kinetic energy.
Therefore, the response is 4.