To find the fifth term of the sequence defined by the explicit formula
\[ a_n = -3 + (n - 1)(2), \]
we will substitute \( n = 5 \) into the formula.
Calculating \( a_5 \):
\[ a_5 = -3 + (5 - 1)(2) \]
First, simplify \( (5 - 1) \):
\[ 5 - 1 = 4 \]
Now, substitute back into the formula:
\[ a_5 = -3 + (4)(2) \]
Next, perform the multiplication:
\[ 4 \times 2 = 8 \]
Now, substitute the result back:
\[ a_5 = -3 + 8 \]
Now, perform the addition:
\[ -3 + 8 = 5 \]
Thus, the fifth term of the sequence is
\[ \boxed{5}. \]