Heat and thermal energy are related concepts in thermodynamics, but they refer to different things:
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Thermal Energy: This is the total energy of all the microscopic particles (atoms and molecules) in a substance due to their random motion. It encompasses both the kinetic energy (due to motion) and potential energy (due to the forces between particles) of those particles. Thermal energy is a state function, meaning it depends on the state of the system (e.g., temperature, pressure, and volume) rather than how the system reached that state.
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Heat: This refers to the transfer of thermal energy between systems or bodies due to a temperature difference. Heat is not a substance or a stored energy; rather, it is energy in transit. When thermal energy moves from a hotter object to a cooler one, we say that heat is being transferred. The unit of heat is typically joules (J), just like thermal energy, but they are conceptually different.
In summary, thermal energy is the energy contained within a system, while heat is the energy that flows as a result of a temperature difference.