If the unknown substance is a white solid with a density calculated to be about 1.7 g/mL, the most likely substance is B. phosphoric acid.
Here's the reasoning:
- Sodium hydroxide has a density of 2.13 g/mL, which is significantly higher than 1.7 g/mL.
- Phosphoric acid has a density of 1.685 g/mL, which is close to 1.7 g/mL and matches the appearance of the unknown as a white solid.
- Water and ethanol are both colorless liquids, not solids.
Therefore, the answer is B. phosphoric acid.