To calculate the change in enthalpy (\( \Delta H \)) for a chemical reaction using bond energies, you can follow these steps:
- Identify the bonds broken and formed in the reaction.
- Use the provided bond energies to calculate the total energy of bonds broken and the total energy of bonds formed.
- Calculate the change in enthalpy using the formula: \[ \Delta H = (\text{Energy of bonds broken}) - (\text{Energy of bonds formed}) \]
Example Calculation
For a hypothetical reaction: \[ \text{Reactants} \rightarrow \text{Products} \]
Suppose the reaction involves breaking and forming the following bonds:
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Bonds broken (assuming):
- 2 O-H bonds (from water or some alcohol)
- 1 C-H bond (from an alkane)
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Bonds formed (assuming):
- 1 O=O bond (from molecular oxygen)
- 1 C=O bond (from a carbonyl compound)
Step-by-Step Calculation
Step 1: Determine the bonds involved.
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Bonds broken:
- \( 2 , \text{O-H} \)
- \( 1 , \text{C-H} \)
Step 2: Calculate energy for bonds broken.
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Energy for \( 2 , \text{O-H} \): \[ 2 \times 464 , \text{kJ/mol} = 928 , \text{kJ/mol} \]
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Energy for \( 1 , \text{C-H} \): \[ 1 \times 411 , \text{kJ/mol} = 411 , \text{kJ/mol} \]
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Total energy of bonds broken: \[ 928 , \text{kJ/mol} + 411 , \text{kJ/mol} = 1339 , \text{kJ/mol} \]
Step 3: Calculate energy for bonds formed.
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Bonds formed:
- \( 1 , \text{O=O} \)
- \( 1 , \text{C=O} \)
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Energy for \( 1 , \text{O=O} \): \[ 1 \times 494 , \text{kJ/mol} = 494 , \text{kJ/mol} \]
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Energy for \( 1 , \text{C=O} \): \[ 1 \times 799 , \text{kJ/mol} = 799 , \text{kJ/mol} \]
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Total energy of bonds formed: \[ 494 , \text{kJ/mol} + 799 , \text{kJ/mol} = 1293 , \text{kJ/mol} \]
Step 4: Calculate \( \Delta H \) for the reaction. \[ \Delta H = (\text{Energy of bonds broken}) - (\text{Energy of bonds formed}) \] \[ \Delta H = 1339 , \text{kJ/mol} - 1293 , \text{kJ/mol} = 46 , \text{kJ/mol} \]
Conclusion
The change in enthalpy (\( \Delta H \)) for this hypothetical reaction is \( +46 , \text{kJ/mol} \), indicating that the reaction is endothermic. Adjust your bonds broken and formed as per the actual reaction you are analyzing.