The kinetic energy of a substance is directly related to its temperature. The higher the temperature, the greater the average kinetic energy of the particles. Based on the temperatures provided:
- Sample 1: 98.2°C
- Sample 2: 46.0°C
- Sample 3: 100.6°C
- Sample 4: 31.4°C
Sample 4, which has a temperature of 31.4°C, has the lowest temperature and therefore the lowest kinetic energy among the samples.
So, the answer is 04 (Sample 4).