To determine which value of \( x \) will make \( (x, 63, 65) \) a Pythagorean triple, we need to check if \( x^2 + 63^2 = 65^2 \).
First, calculate \( 63^2 \) and \( 65^2 \):
\[ 63^2 = 3969 \]
\[ 65^2 = 4225 \]
Now, we can set up the equation:
\[ x^2 + 3969 = 4225 \]
Subtract 3969 from both sides:
\[ x^2 = 4225 - 3969 \]
Calculate the right side:
\[ 4225 - 3969 = 256 \]
So, we have:
\[ x^2 = 256 \]
Taking the square root of both sides gives:
\[ x = 16 \]
Thus, the value of \( x \) that makes \( (x, 63, 65) \) a Pythagorean triple is:
\[ \boxed{16} \]