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The slope of a line is undefined when the two points have the same x-coordinate, indicating a vertical line.
Let's analyze the options:
A. (-1,1) and (1,-1) - Different x-coordinates.
B. (-2,2) and (2,2) - Different x-coordinates.
C. (-3,-3) and (-3,3) - Same x-coordinates (undefined slope).
D. (-4,-4) and (4,4) - Different x-coordinates.
The correct answer is **C. (-3,-3) and (-3,3)**, as these points have an undefined slope.