To find the combined mass of the two skyscrapers, you simply add their masses together:
\[ (2.2 \times 10^5 \text{ tons}) + (3.7 \times 10^5 \text{ tons}) \]
First, we can add the coefficients:
\[ 2.2 + 3.7 = 5.9 \]
Now, since both values are in \(10^5\), we can write:
\[ 5.9 \times 10^5 \text{ tons} \]
Therefore, the combined mass of the two skyscrapers in scientific notation, expressed to one decimal place, is:
\[ \boxed{5.9 \times 10^5} \text{ tons} \]