To find the undefined value for the equation
\[ 22 = 4 + \frac{5x}{9x - 6}, \]
we need to determine when the fraction \(\frac{5x}{9x - 6}\) is undefined. A fraction is undefined when its denominator is equal to zero. Thus, we set the denominator equal to zero and solve for \(x\):
\[ 9x - 6 = 0. \]
Adding 6 to both sides gives:
\[ 9x = 6. \]
Now, dividing both sides by 9:
\[ x = \frac{6}{9} = \frac{2}{3}. \]
So, the undefined value for \(x\) is
\[ \frac{2}{3}. \]
Thus, the answer is:
\[ \frac{2}{3}. \]