Here are the answers to the questions based on the information provided:
Question 1: Which set of elements has nearly the same atomic radius?
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Answer: (b) Ne, Ar, Kr, Xe
All are noble gases located in the same group and have similar atomic radii.
Question 2: Which ground state electron configuration represents an Na+ ion?
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Answer: (c) 1s² 2s² 2p⁶
Na has an atomic number of 11. Na+ has lost one electron, leaving it with 10 electrons, which corresponds to the electron configuration of Ne.
Question 3: Which pair of atoms and/or ions is isoelectronic?
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Answer: (a) O²⁻ and Cl⁻
Both have 10 electrons, making them isoelectronic.
Question 4: Which description of an orbital is the most accurate?
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Answer: (b) a solved wave function
This is the most accurate statement regarding the mathematical description of atomic orbitals.
Question 5: What is the total number of electrons in the 4d orbitals of a Molybdenum atom at ground state?
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Answer: (a) 8
The electron configuration of Mo (Z=42) is [Kr] 5s² 4d⁴, which means 4d has 4 electrons and there are additional 4 electrons from the 4d sublevel.
Question 6: Which sublevel, when full, corresponds to the lanthanide series of elements?
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Answer: (b) 4f
The lanthanides fill the 4f subshell.
Question 7: How many electrons does the ion Fe³⁺ (A=56, Z=26) have?
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Answer: (a) 23
Fe has 26 protons and electrons; losing 3 electrons results in 23 electrons.
Question 8: Which situation must be true for two electrons to occupy the same orbital?
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Answer: (c) The electrons must have the opposite spin.
According to the Pauli exclusion principle, two electrons can occupy the same orbital only if they have opposite spins.
Question 9: An electron has the following set of quantum numbers: n = 4, l = 1, ml = 0, ms = + 1/2. In which orbital is this electron found?
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Answer: (b) 4p⁵
The values indicate that the electron is in a 4p orbital.
Question 10: How many different values of the magnetic quantum number (ml) are possible for the third energy level (n=3) of an atom?
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Answer: (d) 3
The values of ml for n=3 are -2, -1, 0, +1, +2, so there are a total of 5 possible values.
Question 11: What is the maximum number of electrons in the nth energy level of an atom?
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Answer: (b) 2n²
The formula for the maximum number of electrons in a shell.
Question 12: Which ground state electron configuration represents the element with the highest first ionization energy?
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Answer: (c) 1s² 2s² 2p⁶ 3s²
Neon has the highest ionization energy due to its full outer shell configuration.
Question 13: Which electron configuration belongs to Fe²⁺?
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Answer: (d) 3d⁴
When Fe loses two electrons, it loses them from the 4s before the 3d, resulting in the configuration of 3d⁴.
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