An irrational number is a number that cannot be expressed as a fraction of two integers, and it has a non-repeating, non-terminating decimal expansion.
Now, let's analyze the options you provided:
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The square root of 16 is 4, which is a rational number (it can be expressed as the fraction 4/1).
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85 is also a rational number (it can be expressed as the fraction 85/1).
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37 is again a rational number (it can be expressed as the fraction 37/1).
None of the numbers listed (the square root of 16, 85, and 37) are irrational. All of them are rational numbers. Thus, there are no irrational numbers among your options.