The atomic radius tends to increase as you move down a group in the periodic table and decrease as you move across a period from left to right.
In the provided options, the elements are all alkali metals (group 1) arranged in order of their appearance in the periodic table:
- Li (Lithium) - Period 2
- Na (Sodium) - Period 3
- K (Potassium) - Period 4
- Rb (Rubidium) - Period 5
Since Rubidium (Rb) is the lowest in the group, it has the largest atomic radius among the elements listed.
Therefore, the answer is: a. Rb, Rubidium.