To simplify the expression \(3x + (x + 2)\) using the Associative Property, we can rearrange the terms. The Associative Property states that the way in which numbers are grouped does not change their sum.
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Start with the expression: \[ 3x + (x + 2) \]
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Apply the Associative Property by changing the grouping: \[ (3x + x) + 2 \]
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Now simplify \(3x + x\): \[ 4x + 2 \]
Thus, the simplest equivalent form of the expression \(3x + (x + 2)\) is: \[ \boxed{4x + 2} \]