Zack is using the distributive property.
The distributive property states that \( a(b + c) = ab + ac \). In this case, Zack sees \( 5(10 + 4) \) as \( 5 \times 10 + 5 \times 4 \), which equals \( 50 + 20 \). Thus, he is distributing the multiplication of 5 over the addition of 10 and 4.