To solve the equation \(2x = 20\), we first isolate \(x\) by dividing both sides by 2:
\[ x = \frac{20}{2} = 10 \]
The solution to the equation is \(x = 10\).
In set notation, we can express this as:
\[ {10} \]
Thus, the set of values that make the equation true is \({10}\).