To prepare a standard potassium permanganate solution (KMnO₄) with a concentration of 0.100 mol/dm³, we first need to determine the number of moles we can obtain from the available mass of KMnO₄, which is 3.95 grams.
Step 1: Calculate the number of moles of KMnO₄.
The molar mass of potassium permanganate (KMnO₄) can be calculated as follows:
- Potassium (K): 39.10 g/mol
- Manganese (Mn): 54.94 g/mol
- Oxygen (O): 16.00 g/mol × 4 = 64.00 g/mol
Now, adding these together gives us the molar mass of KMnO₄:
Next, we can calculate the number of moles in 3.95 grams of KMnO₄:
Step 2: Calculate the volume of solution needed to achieve the desired concentration.
We want to prepare a solution with a concentration of 0.100 mol/dm³. We can use the formula:
Rearranging this gives:
Since
Step 3: Choose the appropriate volumetric flask.
We need to prepare 0.250 L (or 250 mL) of the solution. Among the available options, we have:
- 100 L
- 200 L
- 250 L
- 500 L
The most suitable choice is the 250 L volumetric flask, as it matches our required volume.
Summary:
To prepare a 0.100 mol/dm³ solution of KMnO₄, you should use a 250 mL volumetric flask for the 3.95 grams of solid you have, which will yield the desired concentration.