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To find out how much Hugo will have to pay for the jeans in total, we need to add the cost of the jeans to the tax.
The tax is 7% of the cost of the jeans, so we need to find 7% of $45.99.
7% = 7 / 100 = 0.07
0.07 * $45.99 = $3.22
Hugo will have to pay $45.99 + $3.22 = $<<45.99+3.22=49.21>>49.21 for the jeans in total. Answer: \boxed{49.21}.