Asked by science
                A compound is 36.1% water.  After drying off the water, the rest is 40.1% oxygen, 39.8% copper, and 20.1% sulfur.  
            
            
        Answers
                    Answered by
            oobleck
            
    My crystal ball is hazy today. It isn't telling me what question you are asking.
    
                    Answered by
            science
            
    what is the empirical formula
    
                    Answered by
            DrBob222
            
    You didn't ask a question. I suppose you want to solve for the empirical formula. Take a 100 g sample which will give you
40.1 g oxygen, 39.8 g copper, and 20.1 g sulfur.
mols O atoms = 40.1/16 = 2.51
mols S atoms = 20.1/32.1 = 0.626
mols Cu atoms = 39.8/63.54 = 0.626
Now you want to find the ratio of the Cu to S to O atoms with the smallest whole number being 1.00. The easy way to do this is to divide the three numbers by the smallest value; i.e.,
mols O = 2.51/0.656 = 4.00
mols S = 0.626/0.626 = 1.00
mols Cu = 0.626/0.626 = 1.00
so the empirical formula, without the water, is CuSO4. Now, how much water is in the formula. CuSO4.xH2O
100% - 36.1% = 63.9% water. Again, taking 100 g sample we have
63.9 g CuSO4 and 36.1 g H2O.
mols CuSO4 = 63.9/159.6 = 0.400
mols H2O = 36.1/18.02 = 2
Again, dividing by the smallest number we get
mols CuSO4 = 0.400/0.400 = 1.00
mols H2O = 2/0.400 = 5.00 so x in the formula above is 5.00
and the empirical formula is CuSO4.5H2O
    
40.1 g oxygen, 39.8 g copper, and 20.1 g sulfur.
mols O atoms = 40.1/16 = 2.51
mols S atoms = 20.1/32.1 = 0.626
mols Cu atoms = 39.8/63.54 = 0.626
Now you want to find the ratio of the Cu to S to O atoms with the smallest whole number being 1.00. The easy way to do this is to divide the three numbers by the smallest value; i.e.,
mols O = 2.51/0.656 = 4.00
mols S = 0.626/0.626 = 1.00
mols Cu = 0.626/0.626 = 1.00
so the empirical formula, without the water, is CuSO4. Now, how much water is in the formula. CuSO4.xH2O
100% - 36.1% = 63.9% water. Again, taking 100 g sample we have
63.9 g CuSO4 and 36.1 g H2O.
mols CuSO4 = 63.9/159.6 = 0.400
mols H2O = 36.1/18.02 = 2
Again, dividing by the smallest number we get
mols CuSO4 = 0.400/0.400 = 1.00
mols H2O = 2/0.400 = 5.00 so x in the formula above is 5.00
and the empirical formula is CuSO4.5H2O
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