1. All the following are reaction rate units except

a. ∆M s-1
b. -∆M s-1
c. ∆V M-1 ***
d. ∆M min-1

2. Determine the overall reaction order for the reaction whose rate law is as follows: rate=k[O3][ClO]:
a. 0
b. 1 ***
c. 2
d. 3

3. 0.03 moles are produced in a 1.5-L vessel in 3 seconds. The initial reaction rate is
a. 0.007 M/s
b. 0.014 M/s ***
c. 0.14 M/s
d. 200 M/s

User Icon for Bee Bee answered
3 years ago

I need help. I don't understand reaction orders.

User Icon for DrBob222 DrBob222 answered
3 years ago

2. The order of a reaction is the sum of the exponents for each reactant in the rate equation. I see a 1 for each so it is 1st order with respect to ClO^- and 1st order with respect to O3 and 2nd order overall.

3. Note that the units for each answer is the same; i.e., M/s which is mols/L*s.
You have 0.03 mols and 1.5 L so that is 0.03 mols/1.5L = 0.02 mol/L and that is for 3 sec so 0.02 mol/L*s = 0.02/3 = 0.00667 which rounds to 0.007 M/s to one significant figure.

User Icon for Explain Bot Explain Bot answered
11 months ago

1. To determine the correct answer for this question, we need to understand the units of reaction rates. The general formula for the rate of a reaction is:

Rate = ∆[R] / ∆t,

where ∆[R] represents the change in concentration (or pressure for gases) of the reactant or product, and ∆t represents the change in time.

Now, let's analyze each answer choice:

a. ∆M s-1: This is a valid unit for reaction rate, representing the change in concentration (M) per unit time (s).
b. -∆M s-1: This is also a valid unit for reaction rate, representing the negative change in concentration (M) per unit time (s).
c. ∆V M-1: This is an incorrect unit for reaction rate. It represents the change in volume (V) per unit concentration (M).
d. ∆M min-1: This is a valid unit for reaction rate, representing the change in concentration (M) per unit time (min).

Therefore, the correct answer is c. ∆V M-1, since it does not represent a valid unit for reaction rates.

2. To determine the overall reaction order for the given rate law: rate = k[O3][ClO], we need to sum the powers of the reactant concentrations appearing in the rate law.

In this case, we have one reactant, O3, with a power of 1, and another reactant, ClO, also with a power of 1. Adding these powers together, we get an overall reaction order of 1 + 1 = 2.

Therefore, the correct answer is c. 2.

3. The initial reaction rate can be calculated by dividing the change in moles (∆n) by the change in time (∆t):

Rate = ∆n / ∆t.

Given that 0.03 moles are produced in a 1.5-L vessel in 3 seconds, we have ∆n = 0.03 moles and ∆t = 3 seconds.

Plugging these values into the formula, we get:

Rate = 0.03 moles / 3 seconds = 0.01 moles per second.

To convert moles per second to molarity per second (M/s), we need to divide the rate by the volume of the vessel (in liters). In this case, the volume is 1.5 L.

Rate = 0.01 moles / 1.5 liters = 0.0067 M/s.

Rounded to two decimal places, the initial reaction rate is approximately 0.01 M/s.

Therefore, the correct answer is a. 0.007 M/s.