Asked by Anna

Phosphoric acid, H3PO4(aq), is a triprotic acid, meaning that one molecule of the acid has three acidic protons. Estimate the pH, and the concentrations of all species in a 0.250 M phosphoric acid solution.

[H3PO4] = ?
[H2PO4^-] =?
[HPO4^2-]=?
[PO4^3-]=?
[H^+]=?
[OH^-]=?
pH=?

Answers

Answered by DrBob222
Tell me what you don't understand about this.
Answered by Anna
i converted from pKa to Ka for all three values. i don't know where to go from there.
Answered by DrBob222
What about looking at the three Ka values seprately? You notice that they are about 10^5 from each other. That means that the (H^+) is determined primarily by the first ionization. The second and third ionization produce little H^+. So do the first calculation as you would a monoprotic acid and (at least for the time being) ignore the second and third. Do that and see if you can see where to go from there.
Answered by DrBob222
Ka1 is relatively large; probably you will need to solve the quadratic for Ka1.
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