Asked by Kyle

a solution is prepared by mixing 50.0 mL toluene (C6H5CH3 d=0.867 g/mL) with 125 mL Benzene (C6H6 d=0.874 g/mL). assuming that the volumes add upon mixing, calculate the mass percent, mole fraction, molality, and molarity of the toluene.

Answers

Answered by DrBob222
http://www.jiskha.com/display.cgi?id=1420516971#1420516971.1420518334
Answered by Kyle
but how u do it explain please
Answered by Kyle
i don't know how to do it
Answered by DrBob222
I will get you started with mass percent.
mass percent = (grams solute/mass solution)*100 = %

What mass benzene do you have? Use density to calculate that.

What mass toluene do you have? Use density to calculate that.

mass solution - mass toluene + mass benzene.

Now Substitute into mass percent equation above so that
% toluene = (mass toluene/mass solution()*100 = ?

For the others, lean on the definitions which are as follows:
M = molarity = mols/L solution
m = molality = mols/kg solvent
Xtoluene = mols toluene/total mols
mass = volume x density
Answered by Kyle
mass of benzene is 0.874 g/ml

mass of toluene= 0.867 g/mL
Answered by Kyle
is this right: mass percent: toluene 28.4 %

benezene: 7.6%

mole fraction x C6H5CH3: .251

mole fraction of X C6H6 1.619

molality: 2.3 molal
molarity: 1.43 M is that right? idk
Answered by Kyle
need help
Answered by DrBob222
I have bold faced the typo sentence below.

I will get you started with mass percent.
mass percent = (grams solute/mass solution)*100 = %

What mass benzene do you have? Use density to calculate that.

What mass toluene do you have? Use density to calculate that.

<b>mass solution = mass toluene + mass benzene.</b>

Now Substitute into mass percent equation above so that
% toluene = (mass toluene/mass solution()*100 = % toluene

For the others, lean on the definitions which are as follows:
M = molarity = mols/L solution
m = molality = mols/kg solvent
Xtoluene = mols toluene/total mols
mass = volume x density
Answered by Kyle
i figureed is this right DrBOb22

is my ansswers right

mass percent: 43.359/152.6gx100= 28.4%

mass of benzene: 25 mLx .874 g/mL= 109.25 grams

mass of touluene: 50 mLx .867 g/mL= 43.35 grams

molarity: .251 mol/.175 L= 1.43 M

molality: .251 mol/ .10925 kg= 2.30 m
x touluene= .470 mol/1.87 mol= .251 mol

Answered by Kyle

HELP ME WITH THIS ONE WHEN DONE WITH THE OTHER THX
calculate the concentration of CO2 in a soft drink after the bottle is opened and equilibrates at 25C under a CO2 partial pressure of 0.0003 atm.

c=KP henry's law

k=?

P=0.0003 atm. how to solve
Answered by Kyle
is that right answer
Answered by DrBob222
28.4% tolune is right.
Answered by Kyle
what else is right help me
Answered by Kyle
its touluene
Answered by Kyle
what else is right?
Answered by DrBob222
The problem doesn't ask for % benzene.
The mole fraction toluene is right (but I obtained 0.252 when rounded).
mole fraction benzene is not but problem doesn't ask for that. However, it is 1-mols fraction toluene = 1-0.252 = ?

M toluene = mols toluene/L soln and soln is 50 mL + 125 mL = 175 mL or 0.175L
Then mol toluee = 43.35/92 = 0.471 so
M = 0.471/0.175 = ?
They don't ask for M benzene but it's done the same way. mols benzene/0.175 = ?
m = mols/kg solvent = 0.471/kg solvent.
mass is approx 153 so m = about 0.471/0.153 = about 3.08

Answered by DrBob222
k for CO2 is 3.4E-2 mols/L*atm
c=KP
Substitute p of 3.4E-2 for K and 3E-4 for P, solve for C (in M or mols/L)
Answered by an
a solution is made by dissolving 25 g NaCl in enough water to make 1.0 L solution. Assume that density of the solution is 1.0 g/mL. calculate the mass percent, molarity, molality, and mole fraction of NaCl.

help please

25g/58.44g NaCl=.428 mol

1000 grams of solvent H20

25g/58,44 g x100= 42.8 % mass percent

molarity .428 mol/1.0 L= .428 M

molality= .428 mol/1 Kg= .428 molal is that right?

help please
Answered by an
is that right please help me
Answered by DrBob222
25g/58.44g NaCl=.428 mol

1000 grams of solvent H20

25g/58,44 g x100= 42.8 % mass percent
<b> No, you have 25 g NaCl in 1000g which is 2.5 g/100 so it is 2.5%.</b>

molarity .428 mol/1.0 L= .428 M

molality= .428 mol/1 Kg= .428 molal is that right?
<b>The M and m are right.</b>
Answered by an
thanks good night
Answered by an
25g/58.44g NaCl=.428 mol

1000 grams of solvent H20

25g/58,44 g x100= 42.8 % mass percent

molarity .428 mol/1.0 L= .428 M

molality= .428 mol/1 Kg= .428 molal is that right?

help please
ap chemistry - an, Tuesday, January 6, 2015 at 12:47am
is that right please help me
ap chemistry - DrBob222, Tuesday, January 6, 2015 at 12:47am
25g/58.44g NaCl=.428 mol

1000 grams of solvent H20

25g/58,44 g x100= 42.8 % mass percent
No, you have 25 g NaCl in 1000g which is 2.5 g/100 so it is 2.5%.

molarity .428 mol/1.0 L= .428 M

molality= .428 mol/1 Kg= .428 molal is that right?
The M and m are right.

the answer my teacher gave for the molality was .439 m not .428 m
Answered by an
also for the above question the answer for the mole fraction of NaCl is 0.00785 not 0.00766 what i do wrong

moles of NaCl (.428 mol)/ moles of solution (55.9) = 0.00766 what i do wrong?
Answered by an
HELP ME WITH THIS ONE WHEN DONE WITH THE OTHER THX
calculate the concentration of CO2 in a soft drink after the bottle is opened and equilibrates at 25C under a CO2 partial pressure of 0.0003 atm.

c=KP henry's law

k=?

k for CO2 is 3.4E-2 mols/L*atm
c=KP
Substitute p of 3.4E-2 for K and 3E-4 for P, solve for C (in M or mols/L)
P=0.0003 atm. how to solve

not getting answer of 9.3E-6 M
Answered by DrBob222
Yes, and I missed that.
The solution has a mass of 1000 g if the density is 1.0 g/mL but 25g of that is NaCl so the mass solvent is not 1 kg (as I led you to believe) but 1000g-25g = 975g or 0.975 kg.
Then m = mols/kg solvent = 0.428/0.975 = ?
I have answered above that both M and m are right and I'm not going to change all of those duplicate questions and responses. Hope this taks care of it.

I hope this shows you how to get responses. If you show your work we can find the errors faster.
Answered by DrBob222
For the (CO2) I used 3.4E-2 for K in mol/L*atm and 29.41 for K in L*atm/mol (just the reciprocal). Your teacher may have used a different K value. Mine came from Wikipedia. A K of 3.25 mol/L*atm will give you 9.75E-6M
Answered by kyle
tanks
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