Here are the correct matches based on the historical figures and events associated with each description:
- founded St. Augustine - Menendez
- founded Santa Fe - Piralta
- explored the Ohio valley - Smith
- established missions in Arizona - Kino
- explored the southwestern United States - Coronado
- supported the Roanoke Island colony - Raleigh
- established missions throughout California - Serra
- was the governor of the Roanoke Island colony - White
- bought Manhattan Island - Minuit
- was the leader who rescued the Jamestown colony - Smith
Please note, some of the descriptions may have slight overlaps with multiple historic figures, but the pairings above reflect the most commonly recognized matches.