To subtract \( 2(k - 4) - 3(2k - 1) \), we need to distribute the coefficients first.
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Distribute \( 2 \) in the first term: \[ 2(k - 4) = 2k - 8 \]
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Distribute \( -3 \) in the second term: \[ -3(2k - 1) = -6k + 3 \]
Now we can combine these results: \[ 2(k - 4) - 3(2k - 1) = (2k - 8) + (-6k + 3) \]
Now simplify by combining like terms: \[ 2k - 6k - 8 + 3 = -4k - 5 \]
So, the final result is: \[ \boxed{-4k - 5} \]